N-(4-Chlorobenzylidene)-4-methoxyaniline
نویسندگان
چکیده
The title compound, C(14)H(12)ClNO, was prepared by the reaction of 4-methoxy-aniline and 4-chloro-benzaldehyde in ethanol at 367 K. The mol-ecule is almost planar, with a dihedral angle between the two benzene rings of 9.1 (2)° and an r.m.s. deviation from the mean plane through all non-H atoms in the mol-ecule of 0.167 Å.
منابع مشابه
(E)-2-[2-(4-Chlorobenzylidene)hydrazinyl]-4-[3-(morpholin-4-ium-4-yl)propylamino]quinazolin-1-ium bis(perchlorate)
In the title compound, C(22)H(27)ClN(6)O(2) (2+)·2ClO(4) (-), the mol-ecule adopts an E conformation about the C=N double bond. The quinazoline ring is approximately planar, with an r.m.s. deviation of 0.0432 Å, and forms a dihedral angle of 5.77 (4)° with the chloro-phenyl ring. The crystal packing features N-H⋯O hydrogen bonds.
متن کاملtrans-Dichloridobis(4-methoxyaniline-κN)palladium(II)
In the title compound, [PdCl(2)(C(7)H(9)NO)(2)], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak inter-molecular Pd⋯Cl inter-actions, with Pd⋯Cl distances of 3.6912 (6) Å. A chain-like arrangement of mol-ecules realized by inter-molecular N-H⋯Cl h...
متن کاملN-(4-Chlorobenzylidene)-1-naphthylamine
The title compound, C(17)H(12)ClN, represents a trans isomer with respect to the C=N bond; the dihedral angle between the planes of the naphthyl and benzene groups is 66.53 (5)°.
متن کامل(E)-N′-(4-Chlorobenzylidene)-3,4,5-trimethoxybenzohydrazide
The title compound, C(17)H(17)ClN(2)O(4), was synthesized from 3,4,5-trimethoxy-benzohydrazide and 4-chloro-benzaldehyde. In the crystal structure, packing is stabilized by intramolecular C-H⋯O and inter-molecular N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.
متن کاملN′-(4-Chlorobenzylidene)-2-[4-(methylsulfanyl)phenyl]acetohydrazide
In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C-N-N-C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. The dimers are further linked by weak C-H⋯π inter-actions.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008